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Product Title:ADEKA NOL UH-450VF
- Category:thickener
- Product Packing:16kg can
- Active principle:
- Order hotline: +86-21-69191858
Thickener, Rheology Modifier
ADEKA NOL UH-450VF
The use of a thickener or viscosity controller has become an important factor in the formulation of synthetic emulsion paints and synthetic emulsion adhesives. Products of the ADEKANOL UH series from ADEKA are widely used as key thickeners/viscosity controllers and, in such use, impart Newtonian viscosity properties to synthetic paints and/or adhesives.
Our thickener ADEKANOL UH-450 has already found long time use in the Japanese market showing an excellent thickening effect, producing Newtonian shear viscosity as well as good pigment compatibility. Consequently ADEKANOL UH-450 finds use in many different applications.
Besides ADEKANOL UH-450, ADEKA has developed UH-450VF as VOC free type of UH-450. In UH-450VF no *VOC and SVOC raw material is used.
*VOC: Volatile Organic Compound (b.p.= 50-100oC – 240-260oC)
SVOC: Semi Volatile Organic Compound (b.p.= 240-260oC – 380-400oC)
1. Physical properties
UH-450VF | |
Appearance | viscous liquid |
Active content | 30 % |
Ionic property | non ionic |
Viscosity (25 oC) | 23 000 mPa.s |
2. Characteristics
· ADEKANOL UH-450VF has excellent thickening effect
· ADEKA NOL UH series are nonionic, no pH change of the original formulation
· Compatible with HEC and alkaline-swelling type thickeners
· Good pigment compatibility
· Excellent water resistance
· Viscosity of synthetic paints/adhesives follows leveling properties.
3. Addition rate
The suggested addition level is between 0.1 to 1.0% ADEKANOL UH-450VF (solution) based on weight of total formula.
4. Evaluation of synthetic emulsion
4.1 Viscosity increase
4.1.1 Testing method
Add adequate amount of ADEKA NOL UH-450VF and stir well. Leave the emulsion to stand overnight at 25 oC. The viscosity is measured by a Brookfield viscometer (B8H type, 50, 20, 10, 5 rpm). Viscosity data is plotted in Log-Log graph and the shear viscosity properties are calculated from the shape of plot lines as TI (thixotropic index).
Test formulation
Synthetic emulsion: 100 emulsion A for semi-gloss paint
Defoamer (ADEKA NATE B-940): 0.2
Thickener: 0 – 1.0 % (as solution)
Test Thickeners: ADEKA NOL UH-450VF
ADEKA NOL UH-450
ADEKA NOL UH-420
R-82 (obtained from the market)
4.1.2 Results
TI
Solution dosage (wt%) | ||||
0.0 | 0.2 | 0.4 | 1.0 | |
UH-450VF | 0.24 | 0.45 | 0.45 | 0.46 |
UH-450 | 0.24 | 0.46 | 0.45 | 0.47 |
UH-420 | 0.24 | 0.42 | 0.37 | 0.39 |
R-82 | 0.24 | 0.42 | 0.37 | 0.39 |
Fig1. Viscosity increase and TI (evaluation in resin emulsion)
Fig 2. Rheological profile (evaluation in resin emulsion)
ADEKANOL UH-450VF shows excellent thickening effect and leveling property.
5. Evaluation in paint
5.1 Viscosity increase
5.1.1Testing method
ADEKA’s own formulated white paint is used and the same evaluation as above is made.
White paint formulation (wt):
Materials | Ratio | Type, Supplier |
Water | 9.99 | |
Sodium tripolyphosphate | 0.5 | |
ADEKA COL W-193 | 0.5 | Dispersing agent (ADEKA) |
TiO2 | 28.67 | TCR-10 (Tochem) |
ADEKA NATE B-1015 | 0.40 | Defoamer (ADEKA) |
Total Pigment paste | 40.06 |
Emulsion for semi gloss paint | 53.25 | |
Texanol | 2.60 | CS-12 Chisso petro chem |
Propylene glycol | 3.80 | ADEKA |
Ammonia solution (28 %) | 0.10 | |
ADEKANATE B-1015 | 0.19 | Defoaming agent |
Total | 100 |
Test formulation (% wt): 100 % white semi gloss paint
Thickener: appropriate amount (0-1.0 % as solution)
Test thickeners: ADEKA NOL UH-450VF
ADEKA NOL UH-450
ADEKA NOL UH-420
R-82 (obtained from the market)
5.1.2 Results
Solution dosage (wt%) | ||||
0.0 | 0.2 | 0.4 | 1.0 | |
UH-450VF | 0.37 | 0.32 | 0.33 | 0.31 |
UH-450 | 0.37 | 0.31 | 0.32 | 0.31 |
UH-420 | 0.37 | 0.32 | 0.29 | 0.29 |
R-82 | 0.37 | 0.32 | 0.31 | 0.31 |
TI
Fig3. Viscosity increase and TI (evaluation in white paint)
Fig 4: Rheological profile (evaluation in white paint)
ADEKANOL UH-450VF shows leveling flow similar to UH-450 and UH-420.
5.2 Pigment compatibility
5.2.1 Testing method
The thickener is stirred into the white paint and then a colored pigment paste is added. After one night at 25oC the paint is applied on an art-paper and one corner is rubbed with the fingers. After drying, the color difference is compared between the rubbed area and the un rubbed area.
Test pigment and formulation:
Pigment FLTR manufactured by Dainichi Seika (Black paste)
Paint original 100
Thickener appropriate amount to get 3,000 – 5,000 mPa?s viscosity in the paint
Pigment (black) 4
Test thickener ADEKA NOL UH-450VF
ADEKA NOL UH-450
ADEKA NOL UH-540
ADEKA NOL UH-420
H-4 (typical HEC)
5.2.2 Results
Fig 5. Influence on pigment dispersing ability
Pigment compatibility of ADEKA NOL UH-450VF is good.